::Monocyclic monoterpene ketone monooxygenase
::concepts
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Monocyclic monoterpene ketone monooxygenase (EC 1.14.13.105, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with system name (-)-menthone,NADPH:oxygen oxidoreductase.<ref>{{#invoke:Citation/CS1|citation
|CitationClass=journal
}}</ref><ref>{{#invoke:Citation/CS1|citation
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}}</ref><ref>{{#invoke:Citation/CS1|citation
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}}</ref> This enzyme catalyses the following chemical reaction
- (1) (-)-menthone + NADPH + H+ + O2 <math>\rightleftharpoons</math> (4R,7S)-7-isopropyl-4-methyloxepan-2-one + NADP+ + H2O
- (2) dihydrocarvone + NADPH + H+ + O2 <math>\rightleftharpoons</math> 4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
- (3) (iso)-dihydrocarvone + NADPH + H+ + O2 <math>\rightleftharpoons</math> 6-isopropenyl-3-methyloxepan-2-one + NADP+ + H2O
- (4a) 1-hydroxymenth-8-en-2-one + NADPH + H+ + O2 <math>\rightleftharpoons</math> 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
- (4b) 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one <math>\rightleftharpoons</math> 3-isopropenyl-6-oxoheptanoate (spontaneous)
Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD).
Monocyclic monoterpene ketone monooxygenase sections
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{{#invoke:Infobox|infobox}}
Monocyclic monoterpene ketone monooxygenase (EC 1.14.13.105, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with system name (-)-menthone,NADPH:oxygen oxidoreductase.<ref>{{#invoke:Citation/CS1|citation
|CitationClass=journal
}}</ref><ref>{{#invoke:Citation/CS1|citation
|CitationClass=journal
}}</ref><ref>{{#invoke:Citation/CS1|citation
|CitationClass=journal
}}</ref> This enzyme catalyses the following chemical reaction
- (1) (-)-menthone + NADPH + H+ + O2 <math>\rightleftharpoons</math> (4R,7S)-7-isopropyl-4-methyloxepan-2-one + NADP+ + H2O
- (2) dihydrocarvone + NADPH + H+ + O2 <math>\rightleftharpoons</math> 4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
- (3) (iso)-dihydrocarvone + NADPH + H+ + O2 <math>\rightleftharpoons</math> 6-isopropenyl-3-methyloxepan-2-one + NADP+ + H2O
- (4a) 1-hydroxymenth-8-en-2-one + NADPH + H+ + O2 <math>\rightleftharpoons</math> 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
- (4b) 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one <math>\rightleftharpoons</math> 3-isopropenyl-6-oxoheptanoate (spontaneous)
Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD).
Monocyclic monoterpene ketone monooxygenase sections
Intro References External links
PREVIOUS: Intro | NEXT: References |
<< | >> |